Yes, silicone sealant can cure in damp or humid conditions, because most silicone sealants cure by reacting with moisture in the air.
But applying it in the rain is usually a bad idea.
Rain can cause problems before the sealant has skinned over:
- It can wash uncured silicone away
- It can weaken adhesion
- It can trap dirt or water under the bead
- It can leave a messy, uneven surface
- It may cause leaks later even if the silicone eventually cures
For best results, apply silicone sealant to a clean, dry surface, then keep it protected from rain until it forms a skin. Many silicones skin over in 10–30 minutes, but full cure often takes 24 hours or more, depending on thickness, temperature, humidity, and product type.
For outdoor work, use a weatherproof exterior silicone and check the label. Some “rain-ready” or “wet-surface” sealants are designed to tolerate moisture better, but normal silicone should not be applied during active rain.